- anti-Selective Catalytic Asymmetric Nitroaldol Reaction of α-Keto Esters: Intriguing Solvent Effect, Flow Reaction, and Synthesis of Active Pharmaceutical Ingredients
Tomoya Karasawa, Raphaël Oriez, Naoya Kumagai,* and Masakatsu Shibasaki*
J. Am. Chem. Soc. 2018, 140, 12290–12295. - Direct Catalytic Asymmetric 1,6-Conjugate Addition of Amides to p-Quinone Methides
Zhongdong Sun, Bo Sun, Naoya Kumagai,* and Masakatsu Shibasaki*
Org. Lett. 2018, 20, 3070–3073. - Direct Catalytic Asymmetric Aldol Reaction of α-vinyl Acetamide
Toshifumi Takeuchi, Naoya Kumagai,* and Masakatsu Shibasaki*
J. Org. Chem. 2018, 83, 5851–5858. - Direct Enolization Chemistry of 7-Azaindoline Amides: A Case Study of Bis(tetrahydrophosphole)-type Ligands
Zhao Li, Hidetoshi Noda, Naoya Kumagai,* and Masakatsu Shibasaki*
Tetrahedron 2018, 74, 3301–3305. - Catalytic Oligopeptide Synthesis
Zijian Liu, Hidetoshi Noda, Masakatsu Shibasaki,* and Naoya Kumagai*
Org. Lett. 2018, 20, 612–615. - Direct Catalytic Asymmetric Aldol Reaction of Thioamide with an α-Vinyl Appendage
Jin Cui, Akimichi Ohtsuki, Takumi, Watanabe,* Naoya Kumagai,* and Masakatsu Shibasaki*
Chem. Eur. J. 2018, 24, 2598–2601. - Direct Catalytic Asymmetric Mannich-type Reaction En Route to α-Hydroxy-β-Amino Acid Derivatives
Bo Sun, Roman Pluta, Naoya Kumagai,* and Masakatsu Shibasaki*
Org. Lett. 2018, 20, 526–529. - Heterogeneous Heterobimetallic Catalysis Enabling Expeditious Access to CF3‑Containing vic-Amino Alcohols
Tomoya Karasawa, Naoya Kumagai,* and Masakatsu Shibasaki*
Org. Lett. 2018, 20, 308–311. - Structural and Computational Investigation of Intramolecular N−H Interactions in α- and β-Fluorinated 7-Azaindoline Amides
Lennart Brewitz, Hidetoshi Noda, Naoya Kumagai,* and Masakatsu Shibasaki*
Eur. J. Org. Chem. 2018, 714–722. - Bis(2-pyridyl)amides as Readily Cleavable Amides Under Catalytic, Neutral, and Room-Temperature Conditions
Shinya Adachi, Naoya Kumagai,* and Masakatsu Shibasaki*
Synlett 2018, 29, 301–305. - Catalytic Asymmetric Synthesis of α-Trifluoromethylated Carbinols: A Case Study of Tertiary Propargylic Alcohols
Hidetoshi Noda, Naoya Kumagai,* and Masakatsu Shibasaki*
Asian J. Org. Chem. 2018, 7, 599–612. - Conquering Amide Planarity: Structural Distortion and Its Hidden Reactivity
Shinya Adachi, Naoya Kumagai,* and Masakatsu Shibasaki*
Tetrahedron Lett. 2018, 59, 1147–1158.
Exotic Heterocycles