- α,β-Unsaturated Amides as Dipolarophiles: Catalytic Asymmetric Exo-selective 1,3-Dipolar Cycloaddition with Nitrones
Ming Zhang, Naoya Kumagai,*and Masakatsu Shibasaki*
Chem. Eur. J. 2017, 23, 12450–12455. - Catalytic Enantioselective Addition of Diethyl Phosphite to N-Thiophosphinoyl Ketimines: Preparation of (R)-Diethyl(1-amino-1-phenylethyl)phosphonate
Shaoquan Lin, Yasunari Otsuka, Liang Yin, Naoya Kumagai,* and Masakatsu Shibasaki*
Org. Synth. 2017, 94, 313–331. - Direct Catalytic Asymmetric Aldol Addition of an α-CF3 Amide to Arylglyoxal Hydrates
Akinobu Matsuzawa, Hidetoshi Noda, Naoya Kumagai,* Masakatsu Shibasaki*
J. Org. Chem. 2017, 82, 8304–8308. - Photocatalytic α-Acylation of Ethers
Zhongdong Sun, Naoya Kumagai,* Masakatsu Shibasaki*
Org. Lett. 2017, 19, 3727–3730. - Direct N-Acylation of Sulfoximines with Carboxylic Acids Catalyzed by the B3NO2 Heterocycle
Hidetoshi Noda, Yasuko Asada, Masakatsu Shibasaki,* and Naoya Kumagai*
Chem. Commun. 2017, 53, 7447–7450. - α-Halo Amides as Competent Latent Enolates: Direct Catalytic Asymmetric Mannich-type Reaction
Bo Sun, Pandur Venkatesan Balaji, Naoya Kumagai,* and Masakatsu Shibasaki*
J. Am. Chem. Soc. 2017, 139, 8295–8301. - Cu/Pd Synergistic Dual Catalysis: Asymmetric α-Allylation of α-CF3 Amide
Akira Saito, Naoya Kumagai,* and Masakatsu Shibasaki*
Angew. Chem., Int. Ed. 2017, 56, 5551–5555. - Catalytic Asymmetric Synthesis of CF3-Substituted Tertiary Propargylic Alcohols via Direct Aldol Reaction of α-N3 Amide
Hidetoshi Noda, Fuyuki Amemiya, Karin Weidner, Naoya Kumagai,* and Masakatsu Shibasaki*
Chem. Sci. 2017, 8(4), 3260–3269. - Reversible Stereoselective Folding/Unfolding Fueled by the Interplay of Photoisomerism and Hydrogen Bonding
Christopher R. Opie, Naoya Kumagai,* and Masakatsu Shibasaki*
Angew. Chem., Int. Ed. 2017, 56, 3349–3353. - Unique Physicochemical and Catalytic Properties Dictated by the B3NO2 Ring System
Hidetoshi Noda, Makoto Furutachi, Yasuko Asada, Masakatsu Shibasaki,* and Naoya Kumagai*
Nature Chem. 2017, 9, 571–577. - Asymmetric Flow Catalysis: Mix-and-Go Solid-Phase Nd/Na Catalyst for Expeditious Enantioselective Access to a Key Intermediate of AZD7594
Akihito Nonoyama, Naoya Kumagai,* and Masakatsu Shibasaki*
Tetrahedron 2017, 73, 1517–1521. - Direct Catalytic Asymmetric Aldol Reaction of α-Alkylamides
Zijian Liu, Toshifumi Takeuchi, Roman Pluta, Fernando Arteaga Arteaga, Naoya Kumagai,* and Masakatsu Shibasaki*
Org. Lett. 2017, 19, 710–713. - Catalytic Asymmetric Synthesis of 2,3,3,3-Tetrafluoro-2-Methyl-1-Arylpropan-1-Amines as Useful Building Blocks for SAR-Studies
Lennart Brewitz, Naoya Kumagai,* and Masakatsu Shibasaki*
J. Fluor. Chem. 2017, 194, 1–7. - Pyramidalization/Twisting of the Amide Functional Group via Remote Steric Congestion Triggered by Metal Coordination
Shinya Adachi, Naoya Kumagai,* and Masakatsu Shibasaki*
Chem. Sci. 2017, 8, 85–90. - Strategic Immobilization of Molecular Catalysts onto Carbon Nanotubes via Noncovalent Interaction for Catalytic Organic Transformation
Naoya Kumagai* and Masakatsu Shibasaki*
Isr, J. Chem. 2017, 57, 270–280.
Exotic Heterocycles